| HS Code | 897768 |
| Polymer Type | Polypropylene Homopolymer |
| Density | 0.900 g/cm³ |
| Melt Mass Flow Rate | 3.5 g/10 min (230°C/2.16 kg) |
| Tensile Strength At Yield | 35.9 MPa |
| Tensile Elongation At Yield | 10% |
| Flexural Modulus | 1550 MPa |
| Notched Izod Impact Strength | 27 J/m (23°C) |
| Heat Deflection Temperature | 100°C (0.45 MPa) |
| Vicat Softening Temperature | 152°C |
| Rockwell Hardness | 102 R |
| Molding Shrinkage | 1.5–2.0% |
| Melting Temperature | 160–165°C |
As an accredited Polypropylene Homopolymer PP L5E89 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Polypropylene Homopolymer PP L5E89 is supplied in 25 kg moisture-resistant woven bags, palletized and stretch-wrapped for transport. |
| Container Loading (20′ FCL) | Polypropylene Homopolymer PP L5E89, bagged and palletized, loaded securely into a clean, dry 20-foot FCL container for ocean shipment. |
| Shipping | Polypropylene Homopolymer PP L5E89 is shipped as non-hazardous polymer pellets in sealed 25 kg bags or jumbo bags, palletized in dry containers or trucks. Keep dry, cool, ventilated, and away from direct sunlight, ignition sources, moisture, and contamination during handling and transport. |
| Storage | Store in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and ignition sources. Keep containers tightly closed and protect from moisture, dust, and contamination. Separate from strong oxidizing agents. Avoid prolonged high temperatures and static buildup; use appropriate grounding. Follow the manufacturer’s SDS and local regulations. |
| Shelf Life | PP L5E89 shelf life is typically 24 months when stored dry, below 30°C, in unopened original packaging, away from sunlight. |
Thin-wall rigid packaging injection moulding with PP-H L5E89 begins with melt temperature control at 230–250 °C and a water-cooled mould face maintained at 20–40 °C. Nominal wall sections for dairy cups, deli containers, and round food pails fall between 0.45 mm and 1.20 mm; the material reaches complete filling only when the gate-freezing time is longer than the pressure-limited flow time. L5E89 is a homopolymer injection moulding grade with a nominal melt flow rate near 4.0 g/10 min under ISO 1133-1:2022 at 230 °C and 2.16 kg; producer certificates commonly record lot values in the 3.5–4.5 g/10 min band. When the flow-length-to-wall-thickness ratio exceeds 160:1, short shots appear at the last cavities unless injection velocity is increased above 250 mm/s. The screw should use a compression ratio of 2.0:1–2.8:1 and an L/D of 20:1–25:1. Because polypropylene absorbs almost no moisture, pre-drying is unnecessary unless pellets have been stored at relative humidity above 60% and surface condensation is present.
Mechanical performance of thin-wall packaging is governed by top-load rigidity rather than tensile yield alone. Under ISO 527-2 at 50 mm/min, L5E89 homopolymer PP typically records tensile yield stress of 32–36 MPa and elongation at yield of 8–12%. Flexural modulus under ISO 178 at 2 mm/min is typically 1,300–1,800 MPa, which allows thin-wall containers to pass industrial top-load testing conducted at 23 °C on a universal tester; the absolute force depends on body geometry, rib pattern, and wall stock. Notched Izod impact under ISO 180/A at 23 °C is usually 2.0–3.5 kJ/m²; at -20 °C the value drops below 1.5 kJ/m², so freezer-grade containers may need impact modification. For food-contact compliance, the moulded part must satisfy overall migration limits under EU Regulation (EU) No 10/2011, olefin polymer provisions under FDA 21 CFR 177.1520, and Chinese food-contact plastic requirements under GB 4806.6-2016.
| Regulatory instrument | Scope | Key requirement |
|---|---|---|
| EU Regulation (EU) No 10/2011 | Plastic food-contact articles | Overall migration < 10 mg/dm² under simulant conditions |
| FDA 21 CFR 177.1520 | Olefin polymers for food contact | No food-type restriction when used per conditions of use A–H |
| GB 4806.6-2016 | Food-contact plastic resins in China | Overall migration < 10 mg/dm²; specific migration limits apply |
| REACH EC 1907/2006 | SVHC communication | SVHC < 0.1% w/w per article |
| RoHS 2011/65/EU | Electrical and electronic equipment | Pb < 1000 mg/kg, Cd < 100 mg/kg, Hg < 1000 mg/kg |
| IEC 60695-11-10 | Flammability of end-use enclosures | HB at 1.6 mm for unfilled L5E89; V-0 requires FR compounding |
Injection moulding of L5E89 closures on 24–96 cavity hot-runner tools uses melt temperature 240–260 °C, mould temperature 10–30 °C, and cooling time 6–10 s for thread walls of 1.5–2.5 mm. The limiting failure mode is not short-term tensile rupture but stress relaxation of the tamper-evident band and thread engagement. At application torque values of 1.8–2.2 N·m on 28 mm PCO 1881 neck finishes, the thread flanks experience sustained compressive stress; creep at 23 °C reduces band tension and can drop removal torque below 0.8 N·m within 48 h if the thread root radius is below 0.35 mm or if moulded-in stress from gate blush is present. Hot-runner valve pins should be set to avoid injection pressure spikes above 120 MPa, because excessive shear at the gate freezes in molecular orientation that later relaxes and contributes to torque loss.
Torque retention is verified under ASTM D2063 or equivalent capping-head protocols with a calibrated torque transducer; the pass window for still water closures is usually 0.8–1.5 N·m removal torque after 24 h at 23 °C. Carbonated beverage closures add a 0 °C drop-impact requirement; homopolymer L5E89 at 0 °C can exhibit notched Izod values below 2.0 kJ/m², so lined closures for carbonated drinks are often downgauged or blended with 5–15 wt% ethylene-propylene copolymer unless the tooling uses a wide tamper-evident bridge geometry. Moulders should avoid regrind levels above 20 wt% because repeated heat histories lower the chain entanglement density and reduce torque-retention stability. If the closure is coloured with organic pigments, pigment dispersion must be checked under ISO 18553 because agglomerates larger than 0.25 mm at the thread root act as stress concentrators.
In white-goods and small-appliance moulding, L5E89 is processed into detergent dispenser bodies, vacuum cleaner dust compartments, iron shells, and rigid kitchen storage containers at wall sections from 2.0 mm to 3.5 mm. Melt temperature is held at 220–240 °C, and mould temperature is set at 30–50 °C to balance surface gloss, crystallinity, and ejection consistency. Screws with 20:1–25:1 L/D and compression ratio 2.0:1–2.8:1 are standard; check-ring wear on machines with accumulated shot counts above 500,000 cycles produces cushion instability and gate-area sink marks in thick bosses. Vacuum dust container bodies benefit from the low moisture uptake of polypropylene: after 24 h immersion at 23 °C, weight gain is below 0.05%, so pre-drying is unnecessary unless the pellets have been stored in damp silos or exposed to condensation.
The limiting property in these components is not short-term stiffness but environmental stress-cracking under household detergent and bleach solutions. L5E89 homopolymer PP resists pH 2–13 aqueous media at 23 °C under 0.5% imposed strain when evaluated for 24 h in accordance with ISO 4599; however, concentrated oxidizing acids and chlorinated solvents cause surface attack. For appliance enclosures, ignition resistance is only UL 94 HB at 1.6 mm; any component requiring V-2 or better must be compounded with halogen-free intumescent additives, and the processing temperature must then be reset because common ammonium polyphosphate-based FR systems decompose above 210 °C. If the moulded part is used in contact with fatty food, fat migration into the PP surface can reduce surface gloss and make cleaning more difficult; the part should be cleaned under 60 °C alkaline detergent and evaluated for stress cracking after 200 cycles of a dishwashing test.
Replacement of HDPE with L5E89 in stackable pallets, dairy crates, bakery trays, and fruit boxes is justified only when the higher flexural modulus of PP-H is needed to reduce wall stock or increase load-bearing rigidity. HDPE typically shows a flexural modulus of 800–1,200 MPa, while L5E89 homopolymer PP is specified at 1,300–1,800 MPa under ISO 178. The trade-off is lower impact resistance: PP-H L5E89 notched Izod at 23 °C is generally 2.0–3.5 kJ/m² under ISO 180/A, but at 0 °C the value can fall to 1.0–1.8 kJ/m², making loaded crate drop performance more sensitive to gate and rib design than HDPE. For the same part geometry, L5E89 may allow a wall-stock reduction of 10–15% relative to HDPE without loss of top-load capacity, but this must be confirmed by finite element analysis and physical stack testing.
Moulding cycles for solid crates with 3–6 mm nominal walls require melt temperature 220–250 °C, mould temperature 20–40 °C, and holding pressure 50–70% of injection pressure until gate freeze. Sink marks at boss intersections are controlled by rib-to-wall ratio not exceeding 0.6:1 and by gas-channel coring in pallet decks thicker than 8 mm. Post-mould shrinkage of L5E89 homopolymer PP is anisotropic; linear mould shrinkage in the flow direction is typically 1.2–1.5% and in the transverse direction 1.3–1.6%. Stacked load capacity is commonly verified with a 6:1 dynamic compression ratio at 23 °C for 24 h, but continuous load at temperatures above 80 °C accelerates creep and may exceed acceptable deflection limits. The ultraviolet resistance of unfilled L5E89 is insufficient for outdoor pallet use; a hindered amine light stabilizer package should be specified for exposure beyond 1,000 h under ISO 4892-2, otherwise surface crazing begins at weld lines and gate scars.
High-cavity disposable cutlery production from L5E89 exposes the shear-viscosity limits of homopolymer PP in sprueless valve-gated systems. On 32–64 cavity cutlery tools with melt temperature 230–250 °C and mould temperature 20–30 °C, the apparent shear rate at the gate can exceed 10,000 s⁻¹. Capillary rheometry for a 4 g/10 min PP-H at 230 °C typically records apparent viscosity of 250–450 Pa·s at 1,000 s⁻¹, dropping to 80–150 Pa·s at 5,000 s⁻¹ because of shear thinning. L5E89 lot-specific high-shear viscosity should be confirmed from the producer's rheology certificate when hot-runner manifold pressure is above 25 MPa; published data for this specific configuration is limited.
Flatware warpage after ejection is driven by differential cooling between the outer surface and the thick core at the handle junction. Mould temperature differentials should be kept below 5 °C across the cavity, and cooling time should be set so that average part ejection temperature does not exceed 65 °C. Injection velocity profiles are set with a fast initial filling segment to prevent flow hesitation, followed by a reduced final fill segment to avoid flash at the fork tine tips. Cutlery made from L5E89 can be tested for flexural strength under ISO 178 and for food-contact migration under EU 10/2011; when hot liquid contact is intended, PP-H homopolymer is limited to continuous use below 100 °C because Vicat softening under ISO 306/A50 is reported at 150–155 °C, and deflection under load occurs well below that. Fork tine tips should be designed with a minimum tip radius of 0.5 mm to avoid brittle fracture during side-load tests.
| Application | Melt temperature | Mould temperature | Wall section | Critical control parameter |
|---|---|---|---|---|
| Thin-wall packaging | 230–250 °C | 20–40 °C | 0.45–1.20 mm | Flow-length ratio and gate freeze |
| Caps and closures | 240–260 °C | 10–30 °C | 1.5–2.5 mm | Gate blush and torque retention |
| Appliance housings | 220–240 °C | 30–50 °C | 2.0–3.5 mm | Check-ring wear and sink marks |
| Pallets and crates | 220–250 °C | 20–40 °C | 3–6 mm | Anisotropic shrinkage and rib ratio |
| Disposable cutlery | 230–250 °C | 20–30 °C | 1.5–3.0 mm | Hot-runner pressure and warpage |
| FR electrical enclosures | 190–215 °C | 30–50 °C | 2.0 mm | FR decomposition and char formation |
Flame-retarded electrical enclosures and appliance back panels use L5E89 as a base resin in combination with intumescent halogen-free systems, typically ammonium polyphosphate, pentaerythritol, and melamine derivatives at total loadings of 25–35 wt%. The processing boundary is set by the decomposition of ammonium polyphosphate, which begins near 210 °C; melt temperature must be controlled in a narrow window of 190–215 °C to prevent acid release and carbonization in the barrel. A water-cooled twin-screw extruder with 40:1 L/D and vacuum degassing below 10 kPa is used for compounding; the strand pelletizer must be operated with low water temperature because FR particles can cause die-face freeze-off. If melt temperature exceeds 220 °C for more than 60 s, the formulation can release gases and produce surface splay during subsequent injection moulding.
Flame performance is evaluated under IEC 60695-11-10 or UL 94 at specimen thickness 1.6 mm; halogen-free PP compounds based on L5E89 can achieve V-0 only when the formulation includes sufficient char-forming synergist and when the moulded part avoids thin ribs. The addition of FR fillers reduces flexural modulus and notched Izod, so enclosure designs should maintain wall sections above 2.0 mm and avoid sharp internal corners. Because the base L5E89 is a homopolymer, UV stabilization with hindered amine light stabilizer packages is required for enclosures installed outdoors; otherwise embrittlement can occur after 1,000 h of accelerated QUV ageing under ISO 4892-2. Material processed outside this window should be quarantined and checked for pH drop, because acidic decomposition residues from FR masterbatch can etch mould steel and lead to sticking on the A-side of the tool.
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Polypropylene Homopolymer PP L5E89 is a low melt mass-flow-rate extrusion resin manufactured for oriented tape, raffia, monofilament, and woven-sack production. The model designation does not follow a universal coding standard, but supplier literature identifies the grade as a narrow-molecular-weight-distribution homopolymer with a melt mass-flow rate of 3.5 g/10 min under 230 °C/2.16 kg in ISO 1133-1:2022 and a nominal density of 0.905 g/cm³ under ISO 1183-1:2019. Pellet ash content is typically controlled below 0.03 wt% under ISO 3451-1:2019. The resin is formulated with a standard antioxidant stabiliser package and is supplied either as natural pellets or as precompounded black, white, or colour-matched material for tinted woven sacks.
Mechanical property data reported on injection-moulded test specimens normally include tensile yield stress between 34 MPa and 36 MPa under ISO 527-2:2012, flexural modulus between 1450 MPa and 1550 MPa under ISO 178:2019, and Charpy notched impact strength between 2.5 kJ/m² and 3.0 kJ/m² at 23 °C under ISO 179-1:2010. The Vicat softening point by method A50 is typically 152–156 °C under ISO 306:2013. Heat deflection temperature at 0.45 MPa is approximately 95 °C under ISO 75-2:2013. Where North American specifications are used, equivalent tensile testing is often reported under ASTM D638-14, flexural modulus under ASTM D790-17, and notched impact under ASTM D256-10. Values are not directly interchangeable with ISO data because specimen geometry and conditioning differ.
Isotactic index, xylene-soluble fraction, and catalyst residue are additional lot-release parameters used by polymer producers even when not printed on a distributor certificate. For PP L5E89, isotactic index is generally above 96% when measured by heptane insolubles under ISO 9113, and the xylene-soluble fraction at 25 °C is normally below 4 wt% under ISO 16152:2005. A higher xylene-soluble fraction shifts the balance toward lower stiffness and higher creep but can improve tape drawability; producers therefore hold the fraction within narrow internal limits to keep orientation behaviour stable across production lots.
Melt processing of PP L5E89 is normally performed on single-screw extruders with barrier screws and L/D ratios between 30:1 and 34:1. Feed section temperatures are set between 190 °C and 210 °C, compression and metering zones between 225 °C and 245 °C, and adapter and die zones between 240 °C and 260 °C. Under these conditions melt pressure before the screen pack commonly remains between 10 MPa and 18 MPa. Cyclic pressure variation greater than 1.5 MPa is a production-scale fault signal associated with feed throat bridging, worn screw elements, or screen pack blinding; the resulting flow variation appears as tape width drift, draw resonance, and inconsistent resin orientation.
Screen packs for oriented tape lines are often arranged as 60/80/100 mesh or 40/80/120 mesh. A screen pack finer than 120 mesh lowers gel content but increases shear heating and residence time. At melt temperatures above 270 °C, thermo-oxidative chain scission accelerates; prolonged operation in that temperature range can reduce the effective melt mass-flow rate and produce carbonyl-containing degradation species. At melt temperatures below 210 °C, screw torque increases and unmelted pellets can survive to the die lip, creating hard particles that break tapes during hot stretching.
For a 75 mm extruder with L/D 32:1, tape lines running PP L5E89 typically hold screw speed between 50 rpm and 90 rpm, with output from 150 kg/h to 250 kg/h. For a 90 mm extruder, output can reach 300 kg/h provided the downstream stretching oven and winders are sized accordingly. Published data for this specific configuration is limited, and actual throughput is determined by die width, tape denier, and haul-off speed.
In water-bath tape production, the quench bath is typically held at 30–35 °C with a control tolerance of ±2 °C. Too-low bath temperature freezes the sheet surface before full crystallisation and can generate differential shrinkage; too-high bath temperature reduces cooling rate and produces blocking on haul-off rolls. The die gap is commonly set from 0.8 mm to 1.0 mm. Primary draw ratio in the orienting oven is held between 5.5:1 and 7.5:1. Draw ratios above 8:1 may cause premature fibrillation, while draw ratios below 5:1 yield tapes with insufficient tenacity for heavy-duty sack construction. Hot-stretch oven temperatures generally fall between 120 °C and 160 °C, with downstream annealing or relaxation of 3–6% to limit shrinkage.
If the sheet enters the quench bath at 45–55 °C surface temperature, the cooling rate is sufficient to develop a spherulitic skin that resists orientation but not so high that the sheet freezes too rapidly and becomes brittle. When quench water temperature drifts beyond ±2 °C, processors commonly observe a change in tape width of 0.5–1.5 mm across a 2.5 mm slit width, and the variation maps directly to non-uniform fabric weight in circular looms. Melt strength of PP L5E89 is higher than that of a 25 g/10 min injection homopolymer, but the exact value depends on temperature and acceleration. In tape extrusion, this difference appears as a wider stable operating window for draw ratio before draw resonance starts.
PP L5E89 differs from high-flow homopolymers mainly in melt mass-flow rate and processing behaviour. A high-flow injection grade with an MFR of 25–35 g/10 min permits shorter injection cycles and lower injection pressure, but its low melt strength makes it unsuitable for water-bath tape orientation. In contrast, the 3.5 g/10 min melt mass-flow rate of PP L5E89 supports a stable drawing process and reduces draw resonance. Compared with random copolymers used in clear film or sealing layers, the homopolymer has higher stiffness and a higher Vicat softening point, but it has a higher heat seal initiation temperature and much lower optical clarity. Compared with impact copolymers containing an ethylene-propylene rubber phase, PP L5E89 lacks sub-ambient impact toughness; the Charpy notched impact at -20 °C is generally below 2.0 kJ/m² under ISO 179-1:2010, whereas impact copolymer grades often remain above 8–12 kJ/m².
The following comparative ranges are drawn from supplier technical data sheets and ISO-conditioned laboratory data for each polymer family. Values should not be used as acceptance limits without consulting the specific lot certificate.
| Property | PP L5E89 | High-flow homopolymer | Random copolymer | Impact copolymer |
|---|---|---|---|---|
| Melt mass-flow rate, 230 °C/2.16 kg (ISO 1133-1:2022) | 3.5 g/10 min | 25–35 g/10 min | 8–12 g/10 min | 2–6 g/10 min |
| Tensile yield stress (ISO 527-2:2012) | 34–36 MPa | 32–36 MPa | 24–28 MPa | 20–25 MPa |
| Flexural modulus (ISO 178:2019) | 1450–1550 MPa | 1300–1500 MPa | 800–1000 MPa | 900–1200 MPa |
| Charpy notched impact, 23 °C (ISO 179-1:2010) | 2.5–3.0 kJ/m² | 2.0–2.5 kJ/m² | 8–12 kJ/m² | 15–25 kJ/m² |
| Vicat softening point A50 (ISO 306:2013) | 152–156 °C | 150–155 °C | 125–135 °C | 145–152 °C |
| Heat seal initiation | above 150 °C | not applicable | 110–125 °C | not applicable |
| Optical clarity | opaque to translucent | translucent | transparent | opaque |
For applications requiring high flow and thin-wall injection moulding, PP L5E89 is not a direct replacement; the higher melt viscosity increases injection pressure and can leave flow marks in thin sections. For applications requiring low-temperature impact or transparent sealing layers, the grade should not be used without multilayer coextrusion or component blending.
PP L5E89 is supplied as hydrophobic pellets, and ambient moisture uptake is generally low. However, when stored at relative humidity above 60%, surface moisture can be absorbed in sufficient quantity to produce steam bubbles or splay in tape extrusion. Pre-drying at 80–90 °C for 3–4 h in a desiccant dryer is recommended if the lot moisture content exceeds 0.05 wt% by Karl Fischer titration or weight-loss methods. Storage should remain below 50 °C and away from direct sunlight to prevent antioxidant depletion and yellowing. Prolonged heating in contact with copper or copper alloys is avoided in melt processing because copper ions can catalyse thermo-oxidative degradation of unstabilized polypropylene at elevated temperature.
Typical conversion routes for PP L5E89 include tape extrusion followed by circular weaving into tubular or flat fabrics, coating or lamination with low-melting random copolymer, and sack fabrication by cutting, sewing, and printing. The tape product is also converted into agricultural twine and rope if the film is slit and fibrillated. In injection-moulded form, the grade is limited to thick-walled articles because of its high viscosity; it is not a general-purpose injection moulding grade.
Regulatory compliance for food-contact woven sacks and bulk packaging depends on the specific additive package and migration test conditions. The following matrix summarises common compliance evaluations, not blanket certifications for every colour concentrate or filler masterbatch.
| Standard or regulation | Scope | Evaluation notes |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers for food contact | Homopolymer PP may be used in contact with food if all additives comply with the applicable finished-article extraction limits. |
| EU 10/2011 | Plastics intended for food contact | Overall migration limit 10 mg/dm² for general food contact; specific migration limits for antioxidants must be checked with the colour and additive masterbatch supplier. |
| GB 9685-2016 | China food-contact additive standard | Individual additives and their specific migration limits must be listed in the formulation disclosure. |
| REACH | EU chemical registration and authorisation | No intentionally added Substances of Very High Concern are required for standard natural PP L5E89. |
| RoHS Directive 2011/65/EU | Hazardous substance restriction in electrical and electronic equipment | Complies at 0.1% threshold for lead, mercury, chromium(VI), PBB, and PBDE when no restricted flame retardant or pigment is added. |
For outdoor woven sacks, UV-stabilised masterbatch addition is necessary at levels specified by the masterbatch supplier, commonly between 2 wt% and 5 wt%, with retained tenacity evaluated by accelerated weathering under ISO 4892-2:2013 or ASTM D2565-23. Without such stabilisation, PP L5E89 homopolymer undergoes chain scission, surface chalking, and tensile loss during continuous sunlight exposure.